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Home » GATE Study Material » Chemical Engineering » Solid Fluid Operations » Freely Moving Particles

Freely Moving Particles

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Freely Moving Particles

Freely Moving Particles

In a real suspension the particle positions are not fixed, so that the particles are able to change their relative positions. This renders the calculation of the settling velocities difficult, because we must know the particle distribution to determine the average particle velocity $ \langle U\rangle$, which is defined by

$\displaystyle \langle U\rangle=\frac 1 N \sum_{i=1}^N U_i.$ (1.32)

For monodisperse suspensions the particle distribution is not known a priori. We must distinguish between two cases
1.
The particles are so small that the continuum hypothesis is only partially fulfilled. Then the particles show an erratic random motion, the so called Brownian motion.
2.
The particles are large enough so that the Brownian motion is neglegible.
The so called P�clet number $ Pe$ provides an estimate whether the Brownian motion of particles may be neglected. The P�clet number compares the ratio of heat advection to heat conduction and is defined by

$\displaystyle Pe=\frac{Ua}{D},$ (1.33)

where $ U$ is a typical velocity of the particle, $ a$ its radius and $ D$ is the thermal diffusion coefficient. For $ Pe \gg 1$ the advective motion of the particle dominates and the Brownian motion can be neglected, whereas for $ Pe\ll 1$ the Brownian motion is dominating and the particle movement will be largely of random nature. In case of low P�clet number we therefore expect to find a locally homogeneous particle distribution. This shows that even if we do not consider interparticle forces, the particle distribution is not known a priori.

There have been many approaches to calculate the average settling velocity of the particles in a suspension. We will briefly describe Batchelor's idea [7] which is based on two-particle interactions.

Batchelor considers a random suspension at low volume fraction $ \phi$. He assumes that the particle distribution is homogeneous and calculates the pair interaction between a test sphere positioned at $ \vec{x}_0$ and all possible positions of particles. The mean settling velocity is then given by

$\displaystyle \langle U \rangle = \frac{1}{N!}\int U(\vec{x}_0,\mathcal{C}_N) P(\mathcal{C}_N\vert\vec{x}_0) \mathrm{d}\mathcal{C}_N,$ (1.34)

where $ \mathcal{C}$ is a configuration of $ N$ spheres, and $ P(\mathcal{C}_N\vert\vec{x}_0)$ is the conditional probability density of a configuration of $ N+1$ particles given that there is a sphere at the position $ \vec{x}_0$.

The main problem is that the integral (1.34) is divergent because the velocity field of a particle decays $ \sim
r^{-1}$. He overcomes this problem by calculating $ U-V$ where $ V$ is the translational velocity due to the nonuniform environment. In this fashion, he finds $ \langle U\rangle$ up to order $ \phi$,

$\displaystyle \langle U \rangle=U_{\mathrm {St}}(1-6.55\phi).$ (1.35)

Although Eq. (1.35) is only valid at low volume fractions, Batchelor's linear approximation of the hindered settling function captures one of the main features of particle suspensions. If the particle volume fraction is increased, the settling of the particles is hindered due to the backflow of liquid caused by the other particles.

For particle volume fractions larger than $ \approx 0.15$ the Eq. (1.35) predicts negative settling velocities, i.e. the particles will rise. This shows that the linear theory must not be applied over the whole range of possible volume fractions. A second order approximation of the hindered settling function would require to take three particle interactions into account. This approach has been taken e.g. by P. Mazur et. al. and Brady et.al. [70,13] and leads to better approximations of the hindered settling function. But in all cases one has to make assumptions on the particle distribution within the suspension.

The calculations of the hindered settling function assume that the particles are distributed homogeneously within the volume. If this is not the case, say due to the initial conditions or generated by inclined walls as shown in Figure 1.1, the calculations are not valid any more. In case of inhomogeneous initial conditions as shown on the left side of Figure 1.1, the backflow generated by the particles is not forced to move through the particles but avoids the region of high particle concentration. Thus the hindered settling effect is reduced. In the case of inclined walls, an initially homogeneous distribution of particles will develop areas of higher concentrations (dark grey in Figure 1.1) and areas of lower particle concentration (light grey), where the upward moving fluid flows without the hindrance of settling particles.

Figure 1.1: Sketch of two situations where the average particle settling velocity is increased due to a inhomogeneous initial particle distribution (left side) or inclined walls (right side). In both cases the backflow generated by the settling particles avoids the particles and the average particle velocity is increased.
\begin{figure}
\begin{center}\leavevmode
\epsfig {file=non_hom_susp,width=.6\textwidth} \end{center}\end{figure}

A similar situation occurs when there are long-range interparticle forces or other physical effects that lead to clustering of the particles. In such cases the hindered settling function does not need to be a monotonically decreasing function of the volume fraction.



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